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50. Rh(II)-Catalysed N2-Selective Arylation of Benzotriazoles and Indazoles using Quinoid Carbenes via 1,5-H Shift

S. Sarkar, S. Bhunya, S. Pan, A. Datta, L. Roy* and R. Samanta* Chem Commun, 2024, 60,


49. Cu-Catalyzed functionalization of Heterocycles through C-H Activations 

S. Pan and R. Samanta  Topics in Heterocyclic Chemistry; Sharma, U. and Maiti, D., Ed.; Springer Nature, 2024. 

(Book Chapter)

48. Recent Progress in Copper-Catalysed C-C Bond Formations via C(sp2)-H Insertions Using Diazo and Related Compounds

S. Bera, S. Jana and R. Samanta* Synthesis. 2024, 56, 29-46.

Synthesis review.tif

47. Weakly Coordinating tert-Amide Assisted Rh(III)-Catalyzed C4-Cyanation of Indoles: Application in Photophysical Studies

S. Sarkar#, A. Biswas#, S. Das, B. Sanyal, R. Sahoo and R. Samanta* Chem Commun, 2023, 5911200-11203.

(#contributed equally) 


46. Rh(II)-Catalyzed Synthesis of N-Aryl 2-Pyridone using 2-Oxypyridine and Diazonaphthoquinone via 1,6-Benzoyl Migratory Rearrangement

S. Pan, S. Kundu and R. Samanta* Org. Lett. 2023, 25, 2873–2877.

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Rh(II)_Pyridone N-Arylation.tif

45. Pd(II)-Catalyzed Oxidative Naphthylation of 2-Pyridone through N-H/C-H Activation using Diarylacetylene as
Uncommon Arylating Agent

S. Bera#, A. Biswas#, J. Pal, L. Roy, S. Mondal and R. Samanta* Org Lett. 2023, 25, 1952-1957. (contributed equally) 

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TOC_OL_pyridone naphthylation 2_edited_e

44. Rh(III)-Catalyzed Weakly Coordinating 2-Pyridone Directed Oxidative Annulation using Internal Alkynes: A Reversal in Selectivity

S. Bera, S. Sarkar, J. Pal and R. Samanta* Org Lett. 2022, 24, 8470-8475.

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Pyridone directed annulation_OL.tif

43. Weakly Coordinating tert-Amide Assisted Ru(II)-Catalyzed Synthesis of Azacoumestans via Migratory Insertion of Quinoid Carbene: Application in Total Synthesis of Isolamellarins

S. Sarkar and R. Samanta* Org Lett., 2022, 24, 4536-4541 .

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Ru cat azacoumestan.tif

42. Cu(II)-Catalyzed Construction of Heterobiaryls using 1-Diazonaphthoquinones: A General Strategy for the Synthesis of QUINOX and Related P,N Ligands

A. Biswas, S. Pan and R. Samanta* Org Lett., 2022, 24, 1631-1636.

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41. Rh(III)-Catalyzed Mild Straightforward Synthesis of Quinoline-Braced Cyclophane Macrocycles via Migratory Insertion

B. Ghosh, S. Bera, P. Ghosh and R. Samanta* Chem Commun, 2021, 57, 13134-13137.

TOC_chem comm_macro.tif

40. Transition Metal Catalysed Direct Construction of 2–Pyridone Scaffolds Through C–H Bond Functionalizations

S. Pan, S. Sarkar, B. Ghosh and R. Samanta* Org. Biomol. Chem. 2021. 19, 10516-10529. (Invited review)


39. Transition metal catalyzed Site-Selective C-H Bond Arylation of Arenes/Heteroarenes using Quinone-Diazides

S. Bera and R. Samanta Handbook of C-H Functionalization; Maiti, D., Ed.; Wiley-VCH:Weinheim, 2021. (Book Chapter)

NJC cover page.jpg

38. Iridium(III)-Catalyzed Intermolecular Mild N-Arylation of Aliphatic Amides Using Quinoid Carbene: A Migratory Insertion-Based Approach

S. Bera, S. Roy, S. C. Pal, A. Anoop* and R. Samanta* ACS Catal. 2021, 11, 10847–10854. 

ACS Catal.tif

37. Recent Quinone Diazide Based Transformations via Metal-Carbene Formation

S. Bera, S. Sarkar and R. Samanta* New J. Chem. 2021, 45, 10135-10149. 

'Invited Review in the special issue of "Emerging Investigators 2021".

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chemical record.jpg

36. Straightforward Construction and Functionalizations of Nitrogen Containing Heterocycles through Migratory Insertion of Metal-Carbenes/Nitrenes

S. Bera, A. Biswas and R. Samanta* Chem. Rec. 2021, 51, 3411-3428. 

Invited "Personal Account" in the special issue on "Transition Metal Catalysis".

Chem Rec TOC.tif

35. A Directing Group Free Pd(II)-Catalysed Desulfitative C6-Arylation of 2-Pyridone using Arylsulfonyl Chloride

U. Karmakar and R. Samanta* Org. Biomol. Chem. 2020, 18, 8079-8083


34. Transition Metal Catalysed Direct C‐H Bond Functionalizations of 2‐Pyridone Beyond C3‐Selectivity

A. Biswas, S. Maity, S. Pan and R. Samanta* Chem. Asian J. 2020, 15, 2092-2109. (Invited Review)

2-Pyridone functionalization.tif

33. Rh(III)-Catalyzed Tandem Indole C4-Arylamination/Annulation with Anthranils: Access to Indoloquinolines

and its Application in Photophysical Studies

A. Biswas, S. Bera, P. Poddar, D. Dhara and R. Samanta* Chem Commun, 2020, 56, 1440-1443.


32. Rh(III)-Catalyzed Straightforward Synthesis of Highly Substituted 2-Pyridones using Fluorinated Diazomalonate

D. Das, G. Sahoo, A. Biswas and R. Samanta* Chem. Asian J. 2020, 15, 360-364.

"Invited Article" for a special issue on "ICOC 2020".

4 phenyl pyridone_Chem Asian J.gif

31. Rh(III)-Catalyzed Straightforward Arylation of 8-Methyl/ Formyl Quinolines using Diazo Compounds

B. Ghosh and R. Samanta* Chem. Commun. 2019, 55, 6886-6889.

8-methyl arylation_chem comm.gif

30. Pd(II)-Catalyzed Direct Sulfonylation of Benzylamines using Sodium Sulfinates

U. Karmakar and R. Samanta* J. Org. Chem. 2019, 84, 2850-2861.


29. Rh(III)-Catalyzed Straightforward Synthesis of Benzophenanthroline and Benzophenanthrolinone Derivatives using Anthranils

A. Biswas, S. Sarkar and R. Samanta* Chem. Eur. J. 2019, 25, 3000-3004.

  • Selected as "hot paper". 

  • Selected as "top 10% most downloaded paper from January 2018-December 2019".


28. Direct Pd(II)-Catalyzed Site-Selective C5-Arylation of 2-Pyridone Using Aryl Iodides

S. Maity, D. Das, S. Sarkar and R. Samanta* Org. Lett. 2018, 20, 5167-5171.

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27. Rh(III)-Catalyzed Direct C8-Arylation of Quinoline N-Oxides using Diazonaphthalen-2(1H)-ones: A Practical Approach towards 8-azaBINOL

B. Ghosh, A. Biswas, S. Chakraborty and R. Samanta* Chem. Asian. J. 2018, 13, 2388-2392.

"Invited Article" for a special issue on "Homogeneous Catalysis from Young Investigators in Asia".

26. Rhodium(III)-Catalyzed Regioselective Direct C4-Alkylation and C2-Annulation of Indoles: Straightforward Access to Indolopyridone

A. Biswas and R. Samanta* Eur. J. Org. Chem. 2018, 1426-1436.

  • Selected as "top 10% most downloaded paper from January 2018-December 2019".

25. Iridium(III) Catalyzed Regiocontrolled Direct Amidation of Isoquinolones and Pyridones

D. Das and R. Samanta* Adv. Synth & Catal. 2018, 360, 379-384.

24. Regiocontrolled Direct C4 and C2-Methyl Thiolation of Indoles under Rhodium Catalyzed Mild Conditions

S. Maity, U. Karmakar and R. Samanta* Chem. Commun. 2017, 53, 12197-12200.

  • Selected as "top 10% highly cited paper for the year 2018".

23. A Mild Rhodium Catalyzed Direct Synthesis of Quinolones from Pyridones: Application in the Detection of Nitroaromatics

A. Biswas, D. Giri, D. Das, A. Dey, S. K. Patra* and R. Samanta* J. Org. Chem. 2017, 82, 10989-10996.

22. Copper Catalyzed Direct, Regioselective Arylamination of N-Oxides: Studies to Access Conjugated π-Systems

A. Biswas, U. Karmakar, S. Nandi and R. Samanta* J. Org. Chem. 2017, 82, 8933-8942.

21. Iridium Catalysed Cascade Synthesis of Oxindoles using Diazo Compound: A Quick Entry to the C7-Functionalized Oxindoles

U. Karmakar, D. Das, and R. Samanta* Eur. J. Org. Chem. 2017, 2780-2788.

20. Rhodium(III)-Catalyzed C6-Selective Arylation of 2-Pyridones and Related Heterocycles Using Quinone Diazides: Syntheses of Hetero-Arylated Phenols

D. Das, P. Poddar, S. Maity, and R. Samanta* J. Org. Chem. 2017, 82, 3612-3621.

19. Copper Catalyzed Regioselective Cascade Alkylation and Cyclocondensation of Quinoline N-Oxides with Diazo esters:  Direct Access to conjugated π-Systems

A. Biswas, U. Karmakar, A. Pal, and R. Samanta* Chem. Eur. J. 2016, 22, 13826-13830.

18. C6-Selective Direct Alkylation of Pyridones with Diazo Compounds under Rh(III)-Catalyzed Mild Conditions

D. Das, A. Biswas, U. Karmakar, S. Chand, and R. Samanta* J. Org. Chem. 2016, 81, 842-848.

Graduate & Postdoctoral Publications:

17. Oxidative Regioselective Amination of Chromones Exposes Potent Inhibitors of Hedgehog Signaling Pathway

R. Samanta, R. Narayan, J. O. Bauer, C. Strohmann, S. Sievers, A.P. Antonchick*

Chem. Commun. 2015, 51, 925-928.


16. Rhodium(III)-Catalyzed Direct Regioselective Synthesis of 7-Substituted Indoles

Z. Song, R. Samanta,  A. P. Antonchick*

Org. Lett, 2013, 15, 5662-5665.


15. Metal-Free Oxidative Carbon-Heteroatom Bond Formation via C-H Bond Functionalization

R. Samanta, K. Matcha and A. P. Antonchick*

Eur. J. Org. Chem., 2013, 5769-5804. [Invited mini-riview; one of the top 25 most accessed articles. Selected as free-access-review]


14. Rhodium(III) Catalyzed Direct Oxidative Cross Coupling at C5 Position of Chromones with Alkenes

R. Samanta, R. Narayan and A. P. Antonchick*

Org Lett., 2012, 14, 6108-6111.


13. Organocatalytic, Intermolecular, Oxidative C-H Bond Amination and hydrazination of simple arenes at Ambient Temperature.

R. Samanta, J. O. Bauer, C. Strohmann and A. P. Antonchick*

Org Lett., 2012, 14, 5518-5521.

  • One of the most read articles in 10/2012–11/2012


12. Metal-Free Direct Oxidative Intermolecular Multiple C–H Bond Functionalizations at Ambient Temperature Assisted by Cascade Selective Formation of C–C and C–N Bonds

R. Samanta, J. Lategahn and A. P. Antonchick*

Chem Commun 2012, 48, 3194-3196.


11. Metal-Free Electrocyclization at Ambient Temperature: Synthesis of 1-Aryl carbazoles.

 R. Samanta, K. Kulikov, C. Strohmann and A. P. Antonchick*

Synthesis 2012, 44, 2325-2332. (Invited Feature Article)

  • One of the 10 most accessed articles in 8/2012.


10. Metal Free Oxidative Amination at Ambient Temperature

Rajarshi Samanta and Andrey P. Antonchick*

Synlett 2012, 23, 809-813. (Invited Highlight)

  • One of the 10 most accessed articles in 3/2012–5/2012


9. Organocatalytic, Oxidative, Intramolecular C-H Bond Amination and Metal-free Cross-Amination of Unactivated Arenes at Ambient Temperature

A. P. Antonchick*, R. Samanta, K. Kulikov, J. Lategahn.

Angew. Chem. 2011, 123, 8764-8767; Angew. Chem. Int. Ed. 2011, 50, 8605-8608.

  • Selected as “hot paper” by the editors

  • Highlighted in SYNFACTS (2011, 1129).

  • One of the most accessed articles in August, 2011 and one of the most accessed articles in first year after publication.


8. Palladium-Catalyzed Double C-H Activation Directed by Sulfoxides in the Synthesis of Dibenzothiophenes.

R. Samanta and A. P. Antonchick*

Angew. Chem. 2011, 123, 5323 – 5326; Angew. Chem. Int. Ed. 2011, 50, 5217 – 5220.

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